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Amphibolites occur in a number of localities in the Cathaysia Block, some of them have been migmatised and their protoliths represent basaltic magmas erupted in various tectonic settings. Four migmatised amphibolites were collected from Jiangxi and Fujian Provinces. Cathodo-luminescence images of zircons extracted from the representative amphibolites show unzoned or sector-zoned structure. LA-ICP-MS analysis indicates that most zircons have high Th/U ratios and yield U–Pb zircon ages of 446 ± 5, 435 ± 2, 434 ± 4 and 423 ± 2 Ma, respectively. Lu–Hf isotopic analysis on these zircons gives Hf model ages ranging from 900 to 1200 Ma. Based on lithological observations and previously published geochronological data, we interpret that these U–Pb ages record an important tectonothermal event that led to the migmatization. This early Paleozoic (Caledonian) tectonothermal event in the Southeastern China has a great tectonic implication for the evolutionary history of the Cathaysia Block.  相似文献   
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Tomcod (Microgadus tomcod) in the St. Lawrence estuarine transition zone (ETZ) undergo an ontogenetic habitat shift. Older age classes, characterised by a male-dominated sex ratio, disperse downstream over the summer months to occupy the colder more saline waters of the estuary. Significant differences in length and mass along the salinity gradient were observed in September with upstream fish of any given age class generally exhibiting greater growth. These differences were not seen in early summer. Benthic amphipod δ 34S signatures were strongly correlated with salinity and served to demonstrate that tomcod δ 34S signatures were not in isotopic equilibrium in the more saline waters of the ETZ. Seasonal distributional patterns, growth dynamics and isotopic disequilibrium all indicate that the observed habitat shift may occur on an annual basis, following winter aggregation in warmer, less saline waters. Tomcod located in the downstream parts of the ETZ, predominantly males, were significantly more sexually developed than upstream tomcod for a given age. On the other hand, greater growth early in life is insured by occupying warmer, upstream waters during the summer months.  相似文献   
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HP/UHP and LT metamorphic units that commonly occur in the inner parts of mountain belts result from the subduction of continental and oceanic material, most often exhumed prior to continental collision. The prograde pressure–temperature history of HP–UHP rocks strongly depends on the convergence rate and on the subduction zone geometry. The maximum pressure recorded provides a proxy for the depth of shearing off and stacking of HP metamorphic nappes. A 2-D thermal model of continental subduction at lithospheric scale is used to compute the length and pressure peak of detached HP metamorphic units as a function of the slab dip angle and the convergence rate. Model results are applied to the metamorphic nappe pile of the inner Alps. A mean convergence rate of 1 cm/year during the subduction of the Briançonnais terrane is indicated by the paleogeographic reconstructions between 46 and 38 Ma. On this basis, the available petrological data and lengths of metamorphic units are used to compute the variations of the slab dip angle. The slab dip angle is shown to increase, from the northeast to the southwest, along the Alpine arc with estimated values of 20° for Suretta, 30–45° for Monte Rosa and Gran Paradiso, and 60° for Dora Maira. From Eocene to Oligocene times, the increase in slab dip angle is controlled by changes of buoyancy, due to the spatial configuration of the Valaisan trough and the incoming of crustal material within the subduction zone.  相似文献   
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http://www.sciencedirect.com/science/article/pii/S1674987111000405   总被引:1,自引:0,他引:1  
This study has focused on the processes of soil degradation and chemical element concentration in tea-growing regions of Rwanda, Africa. Soil degradation accelerated by erosion is caused not only by topography but also by human activities. This soil degradation involves both the physical loss and reduction in the amount of topsoil associated with nutrient decline. Soil samples were collected from eleven tropical zones in Rwanda and from variable depth within each collecting site. Of these, Samples from three locations in each zone were analyzed in the laboratory, with the result that the pH of all soil samples is shown to be less than 5 (pH < 5) with a general average of 4.4. The elements such as iron (Fe), copper (Cu), manganese (Mn), and zinc (Zn) are present in high concentration levels. In contrast calcium (Ca) and sodium (Na) are present at low-level concentrations and carbon (C) was found in minimal concentrations. In addition, elements derived from fertilizers, such as nitrogen (N), phosphorous (P), and potassium (K) which is also from minerals such as feldspar, are also present in low-level concentrations. The results indicate that the soil in certain Rwandan tea plantations is acidic and that this level of pH may help explain, in addition to natural factors, the deficiency of some elements such as Ca, Mg, P and N. The use of chemical fertilizers, land use system and the location of fields relative to household plots are also considered to help explain why tea plantation soils are typically degraded.  相似文献   
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The IAG conducts two programmes, the GeoPT ? proficiency test and a certification programme that are closely interconnected. Both support the quality control/quality assurance activities of geochemical laboratories. Each derives an estimate of ‘true value’ for a number of samples, but arrives at that estimate, and its uncertainty, differently. This review discusses the history of the two programmes and compares the ‘true values’ and their uncertainties obtained through each. It then considers ‘fitness‐for‐purpose’ issues related to both GeoPT ? and certification uncertainties. Issues related to potential modification of the IAG protocol for certification are also considered.  相似文献   
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We analyzed the Se isotopic composition of black shales and related kerogen and sulfide fractions from the Zunyi Ni-Mo-Se deposit, the La’erma Se-Au deposit and the Yutangba Se deposit in southern China to constrain metal sources and accumulation processes, both subjects of disagreement in the scientific community. Se at the Zunyi Ni-Mo-Se polymetallic deposit displayed a restricted range of δ82Se values (−1.6‰ to 2.4‰ with a mean of 0.6‰) suggesting a major hydrothermal origin where aqueous Se was probably transported as H2Se, along with H2S, and precipitated directly as selenides or in sulfides. Se at the La’erma Se-Au deposit covers a larger range in δ82Se values (−3.8‰ to 5.4‰ with a mean of 0.3‰), suggesting Se redistribution following redox transformations, leading to kinetic isotopic fractionation. The largest Se isotopic variation so far in natural terrestrial samples was found in the Yutangba Se deposit, with δ82Se values varying from −12.77‰ to 4.93‰. On the basis of variations in Se isotopes in the deposit, along with other geological and geochemical evidence, the “redox model” (supergene alteration) explains the occurrence of native Se in the deposit. Overall, hydrothermal systems may be a potentially important Se source to form economic deposits in comparison to seawater sources. Significantly, our study indicates that either secondary hydrothermal or supergene alteration is a key factor in Se enrichment in black shales. Redistribution of Se, and probably other redox-sensitive metals like Mo, Cr and V, leads to isotopic fractionation which may be used to fingerprint such alteration/precipitation processes.  相似文献   
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The frequent time‐lapse observations from the life of field seismic system across the Valhall field provide a wealth of information. The responses from the production and injection wells can be observed through time‐shift and amplitude changes. These observations can be compared to modelled synthetic seismic responses from a reservoir simulation model of the Valhall Field. The observed differences between the observations and the modelling are used to update and improve the history match of the reservoir model. The uncertainty of the resulting model is reduced and a more confident prediction of future reservoir performance is provided. A workflow is presented to convert the reservoir model to a synthetic seismic response and compare the results to the observed time‐lapse responses for any time range and area of interest. Correlation based match quality factors are calculated to quantify the visual differences. This match quality factor allows us to quantitatively compare alternative reservoir models to help identify the parameters that best match the seismic observations. Three different case studies are shown where this workflow has helped to reduce the uncertainty range associated with specific reservoir parameters. By updating various reservoir model parameters we have been able to improve the match to the observations and thereby improve the overall reservoir model predictability. The examples show positive results in a range of different reservoir modelling issues, which indicates the flexibility of this workflow and the ability to have an impact in most reservoir modelling challenges.  相似文献   
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